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  • Solid State NMR

Solid State NMR

Ref. 54011
CategoryPhysics and chemistry
To probe the structure of materials using NMR !
  • Duration: 5 weeks
  • Effort: 20 hours
  • Pace: ~4 hours/week
  • Languages: English

What you will learn

At the end of this course, you will be able to:

Understand the major solid-state NMR experiments and how they can be applied to investigate the atomic-level structure and dynamics of solids.

Description

Solid-state NMR has proved to be a powerful tool for the characterization of materials, including battery materials, glasses and catalysts.

 “Solid-state NMR” is the third course of a comprehensive three-part online learning program on NMR. It aims at providing the participants with knowledge about solid-state NMR. In particular, it presents the specific techniques used to acquire and analyze NMR spectra of solids and their applications to probe the structure of different materials.

This course is intended for undergraduate and graduate students as well as educators and professionals who need to gain proficiency as routine users of solid-state NMR.

Format

During the five weeks of the MOOC, you will learn the major solid-state NMR experiments and their applications, through video lectures as well as discussions with other participants and professors through the discussion forum. Through practical courses filmed at the spectrometer, you will also be trained to conduct NMR experiments on spin-1/2 and quadrupolar nuclei in solids. Weekly quizzes will let you test your comprehension of each chapter.

This MOOC is taught in English. However, subtitles in simplified Chinese and Japanese are also provided.

Prerequisites

Participants should have some basic knowledge of NMR spectroscopy and its application for small organic molecules in solution.

Assessment and certification

The acquired knowledge will be tested through practice and graded quizzes, as well as a final exam.
Your final grade is a weighted average of your grades obtained for the graded quizzes and the final exam.
You will earn a certificate for this MOOC provided your final grade is above 65%.

Course plan

  • Week 1: Specific methods for the NMR of solids
  • Week 2: Advanced methods, high-fields and DNP
  • Week 3: Homo-nuclear and hetero-nuclear connectivities and proximities
  • Week 4: NMR of materials and practical course for spin-1/2 nuclei
  • Week 5: Practical course for quadrupolar nuclei

Course team

Olivier Lafon

Categories

Dr. Olivier Lafon is a professor at the University of Lille. The focus of his research is to push the frontiers of solid-state NMR spectroscopy in order to gain unique insights into the structure-property relationships of materials used in the fields of bio-economy, energy and health. His current research interests include the development of novel solid-state NMR methods, notably at high magnetic fields, for quadrupolar nuclei or using Dynamic Nuclear Polarization (DNP), as well as their application for the characterization of materials, including heterogeneous catalysts, porous materials and energy materials. Olivier Lafon received a B.Sc. in physical chemistry from the Ecole Normale Supérieure de Lyon. He obtained MS and PhD degrees from the University of Paris South. He was awarded the Magnetic Resonance in Chemistry Award for Young Scientists by the Euromar scientific committee and became a fellow of the Institut Universitaire de France in 2016. He is the chief science officer of the Lille high-field NMR facility, part of the INFRANALYTICS research infrastructure, and the coordinator of the project to install a 1.2 GHz NMR spectrometer in Lille. He is also member of the editorial board of the journal "Solid-State Nuclear Magnetic Resonance".

Frédérique Pourpoint

Categories

Dr. Frédérique Pourpoint is an assistant professor at the Centrale Lille since 2012. She is working on the development of new methods in solid-state Nuclear Magnetic Resonance (NMR) adapted to nuclei exhibiting close Larmor frequencies including the pair of spins {27Al-13C}. She is using such technique for the local characterization of microporous materials including Metal-Organic Frameworks (MOFs). Her research interests are also focused on the Dynamic Nuclear Polarization method, which allows enhancing the NMR signal.

Julien Trebosc

Categories

Dr. Julien Trébosc is research engineer at CNRS, in charge of a high field NMR spectrometer (800 MHz) since 2005. He is an expert in solid-state NMR, especially regarding quadrupolar nuclei. He develops new pulse sequences that aim at enhancing NMR experiment sensitivity and at measuring a number of structural information on materials at atomic scale. He is mostly focusing on inorganic materials, often observing difficult atoms as low-gamma quadrupolar nuclei (25Mg, 35Cl, 14N, etc) in a broad range of materials (glasses, clays, zeolites etc).

Organizations

University of Lille

Acknowledgements

Dr. Ming Shen, associate professor at East China Normal University, P. R. China, and Dr. Akiko Sasaki, researcher at Bruker BioSpin, Japan are acknowledged for the translation of the subtitles into simplified Chinese and Japanese, respectively.

License

License for the course content

Attribution-NonCommercial-NoDerivatives

You are free to:

  • Share — copy and redistribute the material in any medium or format

Under the following terms:

  • Attribution — You must give appropriate credit, provide a link to the license, and indicate if changes were made. You may do so in any reasonable manner, but not in any way that suggests the licensor endorses you or your use.
  • NonCommercial — You may not use the material for commercial purposes.
  • NoDerivatives — If you remix, transform, or build upon the material, you may not distribute the modified material.

License for the content created by course participants

All rights reserved

"All rights reserved" is a copyright formality indicating that the copyright holder reserves, or holds for its own use, all the rights provided by copyright law.

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